Beilstein J. Org. Chem.2010,6, 1167–1173, doi:10.3762/bjoc.6.133
the Ru(II)–Ru(III) mixed-valence compound [(p-cymene)Ru(μ-Cl)3RuCl2(PCy3)], which was found to be an efficient promoter for atom transfer radical reactions under the adopted experimental conditions.
Keywords: Grubbs catalyst; indenylidene ligands; Kharaschreaction; microwave heating; olefin
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Graphical Abstract
Scheme 1:
Reaction of homobimetallic ruthenium–indenylidene complex 1 with ethylene.